## Example 15.1 # P = 1493.19 MPa # vG = 0.000444 m^3/kg # vD = 0.000284 m^3/kg # bTG = 3.040E-07 / MPa # bTD = 1.600E-08 / MPa # gD = 2867.8 kJ/kmol # n = 12.011 kg/kmol # error = (vG - vD) *P - (vG * bTG - vD * bTD)P^2 / 2 - gD / n ; kJ/mol # Example 15.2 T1 = 25 degC nH2 = 2.0 hfH2 = 0.000 kJ sfH2 = 130.678 kJ/degK nO2 = 1.0 hfO2 = 0.000 kJ sfO2 = 205.148 kJ/degK nH2O = -2.0 hfH2O = -241826.000 kJ sfH2O = 188.834 kJ/degK DH1 = 483652.00 kJ DS1 = 88.836 kJ/degK DG1 = DH1 - T1 * DS1 ; kJ T2 = 2000 degK nH2 = 2.0 hfH2 = 52942.000 kJ sfH2 = 188.419 kJ/degK nO2 = 1.0 hfO2 = 59176.000 kJ sfO2 = 268.748 kJ/degK nH2O = -2.0 hfH2O = -169038.000 kJ sfH2O = 264.769 kJ/degK DH2 = 503136.00 kJ DS2 = 116.048 kJ/degK DG2 = DH2 - T2 * DS2 ; kJ # Example 15.3 R = 8.3145 kJ/degK T1 = 25 degC DG1 = 457166 kJ ln_K1 = - DG1 / R / T1 T2 = 2000 degK DG2 = 271040 kJ ln_K2 = - DG2 / R/ T2 ## Example 15.5 # K = 0.1089 # P_over_P0 = 1.0000 # z = 0.2189 # error = (2* z / (1 - 2* z))^2 * (z / (1 + z)) - K / P_over_P0 # nCO2 = 0.5622 # yCO2 = nCO2 / (1 + z) # nCO = 0.4378 # yCO = nCO / (1 + z) # nO2 = 0.2189 # yO2 = nO2 / (1 + z) # hfCO2 = -393522 kJ # hf_3000_CO2 = 152853 kJ # hf_298_CO2 = 0 kJ # hCO2 = n * (hf + hf_3000 - hf_298) ; kJ # hfCO = -110527 kJ # hf_3000_CO = 93504 kJ # hf_298_CO = 0 kJ # hCO = n * (hf + hf_3000 - hf_298) ; kJ # hfO2 = 0 kJ # hf_3000_O2 = 98013 kJ # hf_298_O2 = 0 kJ # hO2 = n * (hf + hf_3000 - hf_298) ; kJ # HP = -121301.7 kJ # HR = 0 kJ # Q = HP - HR ; kJ # Example 15.6 K = 0.1089 P_over_P0 = 1.0000 z = 0.1553 error = (2* z / (1 - 2* z))^2 * (z / (1 + z)) - K / P_over_P0 nCO2 = 0.6894 yCO2 = nCO2 / (2 + z) nCO = 0.3106 yCO = nCO / (2 + z) nO2 = 1.1553 yO2 = nO2 / (2 + z) # Example 15.7 BEGIN K1 = 0.0020620 K2 = 0.0028930 P_over_P0 = 1.0000 a = 0.0534 b = 0.0551 error1 = ((2*a+b)/(1-2*a-2*b))^2 * (a / (1 + a + b)) - K1 / P_over_P0 error2 = (2*a + b) / (1 + a + b) *(2*b / (1 - 2*a - 2*b))^2 - K2 / P_over_P0 yH2O = (1 - 2*a - 2*b) / (1 + a + b) yH2 = (2*a + b) / (1 + a + b) yO2 = a / (1 + a + b) yOH = 2*b / (1 + a + b) END # Example 15.8 BEGIN K = 0.00042 P_over_P0 = 0.0100 z = 0.2008 yAr = (1 - z) / (1 + z) yArplus = z / (1 + z) yeminus = z / (1 + z) error = yArplus * yeminus / yAr - K / P_over_P0 END # Homework Problems: TBD